diff --git a/datafusion/core/src/physical_planner.rs b/datafusion/core/src/physical_planner.rs
index dc81c9ba9ffde..f41e4b364ef85 100644
--- a/datafusion/core/src/physical_planner.rs
+++ b/datafusion/core/src/physical_planner.rs
@@ -847,6 +847,40 @@ impl DefaultPhysicalPlanner {
                     plan
                 }
             }
+            // A values list is evaluated while it is planned, before the scalar
+            // subqueries have run, so rows with a scalar subquery are projected
+            // from a placeholder row at execution time instead.
+            LogicalPlan::Values(Values { values, schema })
+                if values.iter().flatten().any(contains_scalar_subquery) =>
+            {
+                let placeholder: Arc<dyn ExecutionPlan> =
+                    Arc::new(PlaceholderRowExec::new(Arc::new(Schema::empty())));
+                let rows = values
+                    .iter()
+                    .map(|row| {
+                        let exprs = row
+                            .iter()
+                            .zip(schema.fields())
+                            .map(|(expr, field)| {
+                                Ok(ProjectionExpr {
+                                    expr: create_physical_expr(
+                                        expr,
+                                        schema,
+                                        execution_props,
+                                        planning_ctx,
+                                    )?,
+                                    alias: field.name().clone(),
+                                })
+                            })
+                            .collect::<Result<Vec<_>>>()?;
+                        Ok(Arc::new(ProjectionExec::try_new(
+                            exprs,
+                            Arc::clone(&placeholder),
+                        )?) as Arc<dyn ExecutionPlan>)
+                    })
+                    .collect::<Result<Vec<_>>>()?;
+                UnionExec::try_new(rows)?
+            }
             LogicalPlan::Values(Values { values, schema }) => {
                 let exprs = values
                     .iter()
@@ -2994,6 +3028,11 @@ fn extract_update_assignments(input: &Arc<LogicalPlan>) -> Result<Vec<(String, E
     Ok(assignments)
 }
 
+fn contains_scalar_subquery(expr: &Expr) -> bool {
+    expr.exists(|e| Ok(matches!(e, Expr::ScalarSubquery(_))))
+        .unwrap_or(false)
+}
+
 /// Check if an assignment is an identity assignment (column = column)
 /// These are columns that are not being modified in the UPDATE
 fn is_identity_assignment(expr: &Expr, column_name: &str) -> bool {
diff --git a/datafusion/sqllogictest/test_files/subquery.slt b/datafusion/sqllogictest/test_files/subquery.slt
index 8a6143bc68fbb..4e05a2103ba06 100644
--- a/datafusion/sqllogictest/test_files/subquery.slt
+++ b/datafusion/sqllogictest/test_files/subquery.slt
@@ -2675,6 +2675,18 @@ SELECT (SELECT count(*) FROM sq_empty), (SELECT v FROM sq_values);
 ## Uncorrelated scalar subqueries in various expression contexts
 #############
 
+# VALUES rows with uncorrelated scalar subqueries
+query II
+VALUES ((SELECT min(v) FROM sq_values), 5);
+----
+1 5
+
+query II rowsort
+SELECT * FROM (VALUES ((SELECT max(v) FROM sq_values), 5), (7, (SELECT min(v) FROM sq_values))) AS t(a, b);
+----
+3 5
+7 1
+
 # HAVING clause with uncorrelated scalar subquery
 query II rowsort
 SELECT x, count(*) AS cnt FROM sq_main GROUP BY x